低压密闭消解-电感耦合等离子体发射光谱法测定地质样品中的硼     

杜宝华  盛迪波  罗志翔  王全 《岩矿测试》2020,39(5):690-698

采用酸溶-电感耦合等离子体发射光谱法(ICP-OES)测定地质样品中的全硼量,关键环节在于如何防止样品消解过程中硼元素的损失,降低测量过程中的基体干扰、光谱干扰和记忆效应。基于以上问题,本文采用氢氟酸-硝酸-高氯酸-磷酸在低压密闭溶样罐中消解样品,溶出的硼元素与少量磷酸充分络合,防止硼的挥发损失;以基体及主成分浓度与样品相类似的地质类固体标准物质绘制标准曲线做线性校准,有效匹配和降低样品的基体干扰;采用仪器自带的操作软件,观察分析谱线附近是否存在其他元素的干扰,来确定背景扣除最佳的位置及宽度,降低ICP-OES测量中的光谱干扰;以10%的王水作为进样系统的冲洗液,有效消减测量过程中的记忆效应。当稀释因子为200时,方法的检出限(3SD)为1.2μg/g,定量限(10SD)为4.0μg/g;用岩石、土壤及水系沉积物国家一级标准物质对精密度及准确度进行分析验证,11次测定相对标准偏差为1.8%～7.9%,相对误差为-3.6%～6.3%;以外检分析结果为参考,对硼含量在定量限以上的样品测定,相对误差为-9.3%～12.5%。  相似文献   

Effects of the geometry of two‐dimensional fractures on their hydraulic aperture and on the validity of the local cubic law          下载免费PDF全文

Ahmad Hajjar  Luc Scholtès  Constantin Oltéan  Michel Antoine Buès 《水文研究》2018,32(16):2510-2525

Flow through rough fractures is investigated numerically in order to assess the validity of the local cubic law for different fracture geometries. Two‐dimensional channels with sinusoidal walls having different geometrical properties defined by the aperture, the amplitude, and the wavelength of the walls' corrugations, the corrugations asymmetry, and the phase shift between the two walls are considered to represent different fracture geometries. First, it is analytically shown that the hydraulic aperture clearly deviates from the mean aperture when the walls' roughness, the phase shift, and/or the asymmetry between the fracture walls are relatively high. The continuity and the Navier–Stokes equations are then solved by means of the finite element method and the numerical solutions compared to the theoretical predictions of the local cubic law. Reynolds numbers ranging from 0.066 to 66.66 are investigated so as to focus more particularly on the effect of flow inertial effects on the validity of the local cubic law. For low Reynolds number, typically less than 15, the local cubic law properly describes the fracture flow, especially when the fracture walls have small corrugation amplitudes. For Reynolds numbers higher than 15, the local cubic law is valid under the conditions that the fracture presents a low aspect ratio, small corrugation amplitudes, and a moderate phase lag between its walls.  相似文献   

封闭系统中的白云石化作用过程及其油气地质意义——以南羌塘拗陷中侏罗统布曲组白云岩为例     

孙伟  陈明  万友利  何江林  兰叶芳  卫红伟  陈浩 《地质论评》2020,66(5):1217-1229

南羌塘拗陷中侏罗统布曲组结晶白云岩作为盆地最优质的储层是通过埋藏成岩过程中封闭条件下的白云石化作用形成的，岩石所具有的高孔隙度与封闭系统中白云石化反应有关。根据对羌资11井和羌资12井布曲组的岩石结构分类、碳氧同位素组成及温度计算、流体包裹体均一温度等分析结果，可以认为：结晶白云岩碳同位素值分布区间较窄（2. 86‰~4. 27‰），氧同位素值随着白云石晶体变粗（自形程度变差）逐渐偏负（-3. 27‰~-8. 17‰），显著低于保留原始组构的白云岩，表明结晶白云岩碳源来自于先驱灰岩中的碳，其白云石化作用应是在远离大气水的封闭成岩环境中进行；结晶白云岩流体包裹体均一温度主峰值区间为90~140 ℃，且随着白云石晶粒变粗（自形程度变差），均一温度呈升高的趋势，与氧同位素计算温度变化趋势一致，表明白云石化作用过程是在封闭的条件下进行，白云石随地热增温而生长，并非受外来流体的影响。开放系统中的白云石化作用对油气储集空间的形成没有实际意义，而埋藏成岩过程中封闭系统的白云石化是形成南羌塘拗陷优质储层最为重要的成岩机制。  相似文献   

GNSS多天线基线网单历元模糊度同步解算法     

汤佳明  柴艳菊  闻德保  欧吉坤 《大地测量与地球动力学》2019,39(3):262-268

提出多天线基线网单历元模糊度同步解算法，其具体实现步骤为：1）根据宽巷组合模糊度易于固定的优点，采用附加已知基线长度约束法同步解算各基线的宽巷模糊度，得到dm~cm级精度的近似基线分量；2）将解算得到的各近似基线分量作为约束，同步解算各基线的基频模糊度，以获取mm级精度的基线矢量。该方法的关键在于检验各历元宽巷模糊度解算的正确性，以获取可靠的近似基线分量，为解算各基线的基频模糊度提供准确的基线先验信息。由于动态情况下各历元观测信息比较少，单纯依赖ratio检验不可靠，提出结合基线误差、单位权中误差、基线网模糊度闭合环及ratio值等对多组宽巷模糊度进行检验，避免ratio值设置不当导致模糊度检验中发生纳伪和弃真问题。实测数据结果证明，该处理方法使得模糊度解算的成功率提高1%~2%，可以获取移动平台更丰富的导航信息，提高其服务能力。  相似文献   

Steady‐state analytical solutions of flow and deformation coupling due to a point sink within a finite fluid‐saturated poroelastic layer          下载免费PDF全文

P. Li  K. Wang  G. Fang  D. Lu 《国际地质力学数值与分析法杂志》2017,41(8):1093-1107

An exact steady‐state closed‐form solution is presented for coupled flow and deformation of an axisymmetric isotropic homogeneous fluid‐saturated poroelastic layer with a finite radius due to a point sink. The hydromechanical behavior of the poroelastic layer is governed by Biot's consolidation theory. Boundary conditions on the lateral surface are specifically chosen to match the appropriate finite Hankel transforms and simplify the transforms of the governing equations. Ordinary differential equations in the transformed domain are solved, and then the analytical solutions in the physical space for the pore pressure and the displacements are finally obtained by using finite Hankel inversions. The analytical solutions at some special locations such as the top and bottom surfaces, lateral surface, and the symmetrical axis are given and analyzed. And a case study for the consolidation of a water‐saturated soft clay layer due to pumping is conducted. The analytical solution is verified against the finite element solution. Meanwhile, an analysis of coupled hydromechanical behavior is carried out herein. The presented analytical solution is an exact solution to the practical poroelastic problem within an axisymmetric finite layer. It can provide us a better understanding of the poroelastic behavior of the finite layer due to fluid extraction. Besides, it can be applied to calibrate numerical schemes of axisymmetric poroelasticity within finite domains. Copyright © 2017 John Wiley & Sons, Ltd.  相似文献   

Elastic models for nonlinear response of rigid passive piles     

W. D. Guo 《国际地质力学数值与分析法杂志》2014,38(18):1969-1989

Recent study indicates that the response of rigid passive piles is dominated by elastic pile–soil interaction and may be estimated using theory for lateral piles. The difference lies in that passive piles normally are associated with a large scatter of the ratio of maximum bending moment over maximum shear force and induce a limiting pressure that is ~1/3 that on laterally loaded piles. This disparity prompts this study. This paper proposes pressure‐based pile–soil models and develops their associated solutions to capture response of rigid piles subjected to soil movement. The impact of soil movement was encapsulated into a power‐law distributed loading over a sliding depth, and load transfer model was adopted to mimic the pile–soil interaction. The solutions are presented in explicit expressions and can be readily obtained. They are capable of capturing responses of model piles in a sliding soil owing to the impact of sliding depth and relative strength between sliding and stable layer on limiting force prior to ultimate state. In comparison with available solutions for ultimate state, this study reveals the 1/3 limiting pressure (of the active piles) on passive piles was induced by elastic interaction. The current models employing distributed pressure for moving soil are more pertinent to passive piles (rather than plastic soil flow). An example calculation against instrumented model piles is provided, which demonstrates the accuracy of the current solutions for design slope stabilising piles. Copyright © 2014 John Wiley & Sons, Ltd.  相似文献   

Elastic fields in two joined transversely isotropic media of infinite extent as a result of rectangular loading     

H. T. Xiao  Z. Q. Yue 《国际地质力学数值与分析法杂志》2013,37(3):247-277

This paper presents the closed‐form solutions for the elastic fields in two bonded rocks induced by rectangular loadings. Each of the two bonded rocks behaves as a transversely isotropic linear elastic solid of semi‐infinite extent. They are completely bonded together at a horizontal surface. The rectangular loadings are body forces along either vertical or horizontal directions and are uniformly applied on a rectangular area. The rectangular area is embedded in the two bonded rocks and is parallel to the horizontal interface. The classical integral transforms are used in the solution formulation, and the elastic solutions are expressed in the forms of elementary harmonic functions for the rectangular loadings. The stresses and displacements in the rocks induced by both the horizontal and vertical body forces are also presented. The numerical results illustrate the important effect of the anisotropic bimaterial properties on the stress and displacement fields. The solutions can be easily implemented for numerical calculations and applied to problems encountered in rock mechanics and engineering. Copyright © 2011 John Wiley & Sons, Ltd.  相似文献   

The effect of a storm surge event on the macrophytes of a temporarily open/closed estuary,South Africa     

T. Riddin  J.B. Adams 《Estuarine, Coastal and Shelf Science》2010

Temporarily open/closed estuaries typically open to the sea due to freshwater inflow coupled with storm surge events. In September 2008, in the absence of freshwater inflow, the mouth of the East Kleinemonde Estuary breached in response to a storm surge. The mouth of the estuary closed the following day at a high level. Marine overwash events following the breach introduced large volumes of saline water into the estuary and raised the water level by 0.07–0.33 m. Salinity was significantly higher in the 15 month closed phase after the breach (31 ± 0.9) compared to 21.9 ± 0.9 in the closed brackish phase before the breach. The historical average salinity for the estuary during a closed period is 23–25. The increase in salinity has reduced submerged macrophytes Ruppia cirrhosa and Chara vulgaris cover by 38.1%. Macroalgal cover of species such as Dictyota dichotoma, Caulacanthus ustulatus, Codium tenue and Ulva spp. have increased by 7.9%. The saline high water levels have also significantly reduced supratidal salt marsh cover by 15.2%, and reed and sedge cover by 19.7%. Loss of these habitats may result in bank destabilisation and erosion. This is the first record of an extended saline period in the 15 years the estuary has been monitored. Sea level rise in association with climate change, together with localised freshwater inflow reduction is likely to result in an increase in marine overwash events. The frequency and duration of closed saline periods are likely to increase in this type of estuary. A loss of submerged macrophytes may have significant impacts on faunal composition and abundance and on the subsequent functioning of temporarily open/closed estuaries. This has serious ecological implications since these estuaries represent 70% of the different types of estuaries found in South Africa.  相似文献   

The effects of wastewater discharges on the functioning of a small temporarily open/closed estuary     

Robynne A. Lawrie  Derek D. Stretch  Renzo Perissinotto 《Estuarine, Coastal and Shelf Science》2010

Wastewater discharges affect the functioning of small temporarily open/closed estuaries (TOCEs) through two main mechanisms: (1) they can significantly change the water balance by altering the quantity of water inflows, and (2) they can significantly change the nutrient balance and hence the water quality. This study investigated the bio-physical responses of a typical, small TOCE on the east coast of South Africa, the Mhlanga Estuary. This estuary receives significant inflows of treated effluent from upstream wastewater treatment works. Water and nutrient budgets were used together with biological sampling to investigate changes in the functioning of the system. The increase in inflows due to the effluent discharges has significantly increased the mouth breaching frequency. Furthermore, when the mouth closes, the accumulation of nutrients leads to eutrophication and algal blooms. A grey water index, namely the proportion of effluent in the estuary and an indicator of the additional nutrient inputs into the estuary, reached high values (?50%) during low flow regimes and when the mouth was closed. In these hyper-eutrophic conditions (DIN and DIP concentrations up to 457 μM and 100 μM respectively), field measurements showed that algal blooms occurred within about 14 days following closure of the mouth (chlorophyll-a concentrations up to 375 mg chl-a m⁻³). Water and nutrient balance simulations for alternative scenarios suggest that further increases in wastewater discharges would result in more frequent breaching events and longer open mouth conditions, but the occurrence of hyper-eutrophic conditions would initially intensify despite more frequent openings. The study indicates how water and nutrient balance simulations can be used in the planning and impact assessment of wastewater treatment facilities.  相似文献   

井筒式地下连续墙水平承载能力模型试验研究   总被引：1，自引：0，他引：1  

戴国亮  周香琴  刘云忠  刘立基  龚维明 《岩土力学》2011,32(Z2):185-189

井筒式地下连续墙利用构造接头把地下连续墙段连接成一个平面为封闭形状挡土结构,其刚度大,承载力高。由于基础内部含有大面积的土芯,存在墙内土芯、墙体以及外部土体的相互作用。采用水平单向单循环维持荷载法,通过3个不同截面尺寸的单孔闭合墙水平静载试验,研究闭合地下连续墙基础的水平承载特性。基于墙身内力及位移测试结果,研究了井筒式地下连续墙基础在水平荷载作用下的承载机理,分析了水平荷载-位移特性、墙身位移、墙身弯矩、剪力、转角随深度的分布规律。试验结果表明,闭合墙基础呈整体倾斜破坏特性,墙身弯矩随墙深呈非线性变化,墙身剪力在加载处最大,在墙身弯矩极大值处墙身剪力为0,0点以下,墙身剪力随深度呈“大肚形”变化,并且闭合墙的承载力随着闭合墙边长的增大,深度的提高而提高。  相似文献